Graphene Electronics Applications Get One Step Closer with New Semiconducting Variety

Researchers create "graphene monoxide," which has semiconducting properties

2 min read
Graphene Electronics Applications Get One Step Closer with New Semiconducting Variety

Because graphene lacks an inherent band gap, some critics have claimed that it is a dead-end line of research for electronics. But it's important to note that graphene comes in several varieties.

At the University of Wisconsin-Milwaukee (UWM) researchers have developed a new form of graphene they have dubbed “graphene monoxide (GMO).” With GMO, the UWM researchers believe they have brought graphene electronics applications one-step closer to reality. Instead of merely behaving as a conductor or insulator, the new material is capable of acting like a semiconductor. As a bonus, it also can be mass produced inexpensively.

“A major drive in the graphene research community is to make the material semiconducting so it can be used in electronic applications,” says Junhong Chen, professor of mechanical engineering and a member of the research team. “Our major contribution in this study was achieved through a chemical modification of graphene.”

The research, which was initially published in the journal ACS Nano in November of last year,  didn’t really start off as graphene research at all. Instead it was based around graphene’s forgotten cousin, carbon nanotubes (CNTs).  Chen and his UWM colleagues had developed a hybrid material based around CNTs that they mixed with tin oxide nanoparticles to create sensors.

The researchers wanted to be able to image this hybrid material as it was in the process of sensing. In order to do this they approached Carol Hirschmugl, who had developed an infrared imaging technique. But in order to see more molecules attaching themselves to the CNT, Chen and his colleague Marija Gajdardziska realized that they needed to unroll the CNT, thereby making it graphene.

Once the researchers had made the hybrid material into graphene, they decided to experiment with another cousin of graphene—graphene oxide (GO). GO is essentially layers of graphene that have been stacked on top of one another in an unaligned orientation. One of the experiments they undertook with GO was to put it in a vacuum to reduce the oxygen and heat it. Quite unexpectedly, instead of the material being damaged or even destroyed the unaligned orientation suddenly became aligned. With the addition of heat and a vacuum, GO had become the semiconducting GMO.

“We thought the oxygen would go away and leave multilayered graphene, so the observation of something other than that was a surprise,” says Eric Mattson, a doctoral student of Hirschmugl’s.

While this material they stumbled upon sounds quite promising for further development, it should be noted that the researchers plan to be focusing their attention on determining what the actual trigger mechanism was for the self-ordering of the GMO. In other words, there seems to be a good deal more science to be done before the engineering can begin.

The Conversation (0)

Two Startups Are Bringing Fiber to the Processor

Avicena’s blue microLEDs are the dark horse in a race with Ayar Labs’ laser-based system

5 min read
Diffuse blue light shines from a patterned surface through a ring. A blue cable leads away from it.

Avicena’s microLED chiplets could one day link all the CPUs in a computer cluster together.

Avicena

If a CPU in Seoul sends a byte of data to a processor in Prague, the information covers most of the distance as light, zipping along with no resistance. But put both those processors on the same motherboard, and they’ll need to communicate over energy-sapping copper, which slow the communication speeds possible within computers. Two Silicon Valley startups, Avicena and Ayar Labs, are doing something about that longstanding limit. If they succeed in their attempts to finally bring optical fiber all the way to the processor, it might not just accelerate computing—it might also remake it.

Both companies are developing fiber-connected chiplets, small chips meant to share a high-bandwidth connection with CPUs and other data-hungry silicon in a shared package. They are each ramping up production in 2023, though it may be a couple of years before we see a computer on the market with either product.

Keep Reading ↓Show less