For The First Time, Electronics Printed On Paper Can Be Fully Recycled

Long-lasting devices written with carbon nanomaterial inks can be remade into new ones when their work is done

2 min read
still from a video showing the printing of recyclable electronic circuits on paper
Image: Duke University

With a cocktail of carbon-based inks, engineers have made the first fully printable and recyclable electronic circuits on paper. The sturdy, high-performance devices last for months, and can be decomposed at the end to recover the carbon materials so they can be reused for printing.

The recyclable carbon electronics are not meant to supplant silicon, says Aaron Franklin, an electrical and computer engineering professor at Duke University who reported the advance in Nature Electronics. Instead, this is a way to satisfy the thirst for ubiquitous, embedded electronics without sending enormous amounts of often toxic waste to landfills and the environment.

“It is absolutely not targeted at upending the half-trillion dollar semiconductor industry,” he says. “People want more and more data, and more sensors to capture that data. Be it agricultural or medical or environmental sensors, there’s an increasing appetite for getting electronics all over the place.”

Research on printed and transient electronics has exploded in recent years to meet this demand for low-cost, eco-friendly sensors. Transient electronics are designed to degrade and disappear after use instead of lingering in the body or the environment. But they still create silicon and other waste. Meanwhile, past efforts to print circuits still utilize some techniques outside of the printer, Franklin says. “We emphasize print-in-place. We put the substrate on printer, print everything and then pull it out, and the device is ready to test. And the performance is on par if not better than most other printed transistors.”

To get these high-quality devices, the researchers used carbon inks for all three main elements of thin-film transistors: semiconductor, conductor and insulator. The semiconducting and conductive inks were made from off-the-shelf carbon nanotubes and graphene.

The crucial advance is the researchers’ new insulator ink. For this, they used nanocellulose, an abundant, biodegradable material made from wood pulp. It is used commonly in food packaging, cosmetics and wood products, and sheets of it are also used in electronics as an insulator. But Franklin and his colleagues are the first to suspend nanocellulose in a solution and use it as an ink in printing circuits.

gif of printing Gif: Duke University

With a machine that Franklin describes as an advanced version of a common inkjet printer, the team deposited the three inks onto paper one layer at a time to make transistors. The machine vaporizes the ink into a fine mist of microscopic droplets and guides this aerosol onto the paper surface using an inert gas. But the underlying technique could be transferred to faster roll-to-roll printing, which could churn out thousands of devices quickly.

The devices made had an “astonishingly long shelf life,” he says. “It was genuinely surprising to us.” The bare transistors, without any protective coating or encapsulation, have been sitting on a lab shelf for nine months without any loss in performance, he says.

Recycling the devices involves immersing them in a series of baths, and using sound waves to vibrate them so as to separate all the components. The carbon nanotubes and graphene can be filtered out, and nearly all of it can be recovered to be reused for printing. The nanocellulose and the paper substrate can then be recycled separately.

Franklin says his team haves several applications in mind for the printed carbon electronics that they are now testing. “It’s incredibly promising what these devices can do.”

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3 Ways 3D Chip Tech Is Upending Computing

AMD, Graphcore, and Intel show why the industry’s leading edge is going vertical

8 min read
Vertical
A stack of 3 images.  One of a chip, another is a group of chips and a single grey chip.
Intel; Graphcore; AMD
DarkBlue1

A crop of high-performance processors is showing that the new direction for continuing Moore’s Law is all about up. Each generation of processor needs to perform better than the last, and, at its most basic, that means integrating more logic onto the silicon. But there are two problems: One is that our ability to shrink transistors and the logic and memory blocks they make up is slowing down. The other is that chips have reached their size limits. Photolithography tools can pattern only an area of about 850 square millimeters, which is about the size of a top-of-the-line Nvidia GPU.

For a few years now, developers of systems-on-chips have begun to break up their ever-larger designs into smaller chiplets and link them together inside the same package to effectively increase the silicon area, among other advantages. In CPUs, these links have mostly been so-called 2.5D, where the chiplets are set beside each other and connected using short, dense interconnects. Momentum for this type of integration will likely only grow now that most of the major manufacturers have agreed on a 2.5D chiplet-to-chiplet communications standard.

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