Nanowires Produce More Efficient Thin-Film, Polymer-based Photovoltaics

Last month I submitted a blog entry that suggested if there were a third generation of photovoltaics (first-generation solar cells (single-crystal silicon wafers) and second-generation solar cells (thin-film semiconductors)) using quantum dots that could reach or exceed the 32% Shockley-Queisser Limit than the economics of photovoltaics could improve and their adoption accelerated.

To add to this mix has been recent research at the University of California San Diego in which electrical engineers have added nanowires to polymer-based thin-film photovoltaics to create solar cells that increased the forward bias current by six to seven orders of magnitude as compared to their polymer-only control device.

The work was published in American Chemical Societyâ''s NanoLetters.

When one considers how much cheaper thin-film polymer photovoltaics are compared to single-crystal silicon wafers, and then factor in the possibility of thin-film polymer solar cells becoming orders of magnitude more efficient, things start to look pretty rosy.

But hold on, there remains some pretty fundamental problems, most notably that the polymers begin to degrade quite rapidly when exposed to air. However, the researchers point to work going on around the world to improve the properties of organic polymers that could overcome this problem.

In light of the recent series of entries here and here on this site regarding a potential â''Photovoltaics Mooreâ''s Lawâ'' based on ever decreasing price points as opposed to the ever increasing number of transistors per unit of a chip, and the strong reaction to them, it may be worth adding that we may not have to remain bound to the paradigm of silicon wafers and its incremental improvements.


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