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Carbon Nanotube Speakers Promise Applications Outside of Audio Equipment

It’s been some time since we covered the use of nanomaterials in audio speakers. While not a hotly pursued research field, there is some tradition for it dating back to the first development of carbon nanotube-based speakers in 2008. While nanomaterial-based speakers are not going to win any audiophile prize anytime soon, they do offer some unusual characteristics that mainly stem from their magnet-less design.

Now a group of researchers at Michigan Technological University (MTU) have continued this tradition of tinkering with carbon nanotubes and speakers and walked away winning the Best of Show Award at SAE International’s Noise and Vibration Conference and Exhibition.

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Spintronic Devices Possible Without Magnetic Material

Spintronics, which has offered a promising alternative to electronics, may have just been given a boost that moves it from mere promise to likely future backbone of computing.

A young researcher at Argonne National Laboratory has stumbled upon the amazing discovery that a magnetic material may not be required in order to generate spin current from insulators. The implications of this discovery, which are described in the journal Physical Review Letters, could be far reaching and make possible the continued trend towards ever more powerful computing.

“This is a discovery in the true sense,” said Anand Bhattacharya, a physicist in Argonne's Materials Science Division and the project's principal investigator, in a press release. “There’s no prediction of anything like it.”

The hope of spintronics stems from its use of the spin of electrons to encode information rather than the transport of electrical charge of electrons. This fundamental difference is believed to be a solution to many of the problems associated with electronics, such as high power consumption and the need for more space on a chip.

To date, to be able read the spin of the electrons, which is either “up” or “down,” electrons have had to be held in place in a ferromagnetic insulator material, like yttrium iron garnet (YIG). With the electrons held up momentarily, a heat gradient is applied to the material to set the spin of the electrons in motion again. Once they are spinning across the lattice of the crystal insulator, they start communicating information about the orientation of their spin. In this way, just like an electrical current is a stream of electrons moving through a conductor, a current of pure spin can be achieved in magnetic insulators.

Stephen Wu, the postdoctoral researcher who made the discovery, was looking at different materials that would make it possible to produce smaller spintronic devices and provide greater control over the thermal gradients that needed to be applied to the material to start the current spin of the electrons.

It was during this experimentation with different materials that Wu found himself working with YIG on a substrate of paramagnetic gadolinium gallium garnet (GGG). Because the GGG is a paramagnet and not a ferromagnet, Wu didn’t expect to see any spin because the paramagnet doesn’t generate a magnetic field.

“The spins in the system were not talking to each other. But we still found measurable spin current,” said Wu in the release. “This effect shouldn’t happen at all.”

What the researchers observered, in fact, was that the spin current was stronger in the GGG than in the YIG. It is an amazing scientific discovery, but at this point, the best the scientists can do is speculate regarding why the phenomenon occurs at all.

“We think that there may be other new physics working here,” said Bhattacharya in the release. “Because, since the material is not a ferromagnet, the objects that are moving the spin are not what we typically understand.”

Even while understanding of the physics that explain the phenomenon plays catch up, the researchers see an opportunity to push ahead the state-of-the-art in spintronics.

“We’ve just taken ferromagnetism off its pedestal,” said Wu in the release. “In a spintronic device you don’t have to use a ferromagnet. You can use either a paramagnetic metal or a paramagnetic insulator to do it now.”

Stretchable Conducting Fiber Provides Super Hero Capabilities

The list of potential applications for a new electrically conducting fiber—artificial muscles,  exoskeletons and morphing aircraft—sounds like something out of science fiction or a comic book. With a list like that, it’s got to be a pretty special fiber… and it is. The fiber, made from sheets of carbon nanotubes wrapped around a rubber core, can be stretched to 14 times its original length and actually increase its electrical conductivity while being stretched, without losing any of its resistance.

An international research team based at the University of Texas at Dallas  initially targeted the new super fiber for artificial muscles and for capacitors whose storage capacity increases tenfold when the fiber is stretched. However, the researchers believe that the material could be used as interconnects in flexible electronics and a host of other related applications.

In research published in the journal Science, the team describes how they devised a method for wrapping electrically conductive sheets of carbon nanotubes around the rubber core in such a way that the fiber's resistance doesn’t change when stretched, but its conductivity increases.

You can watch a demonstration in the video below:

“We make the inelastic carbon nanotube sheaths of our sheath-core fibers super stretchable by modulating large buckles with small buckles, so that the elongation of both buckle types can contribute to elasticity, said Ray Baughman, senior author of the paper and director of the Alan G. MacDiarmid NanoTech Institute at UT Dallas, in a press release. “These amazing fibers maintain the same electrical resistance, even when stretched by giant amounts, because electrons can travel over such a hierarchically buckled sheath as easily as they can traverse a straight sheath.”

The researchers have also been able to add a thin coat of rubber to the sheath-core fibers and then another carbon nanotube sheath to create strain sensors and artificial muscles. In this setup, the buckled nanotube sheets act as electrodes and the thin rubber coating serves as the dielectric. Voilà! You have a fiber capacitor.

“This technology could be well-suited for rapid commercialization,” said Raquel Ovalle-Robles, one of the paper’s authors, in the press release. “The rubber cores used for these sheath-core fibers are inexpensive and readily available. The only exotic component is the carbon nanotube aerogel sheet used for the fiber sheath.”

Nanostructured Glass Can Switch Between Blocking Heat and Blocking Light

Electrochromic glass essentially uses electric charge to switch a window from allowing sunlight in to blocking it out. Some have estimated that such “smart windows” could cut lighting needs by about 20 percent and the cooling load by 25 percent at peak times.

Now researchers at the University of Texas Austin have found a way to make them even better. They developed a novel nanostructure architectcure for electrochromic materials that enables a highly selective cool mode and warm mode—something thought to be impossible a few years back.

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Non-Stick Pans Lead the Way to More Efficient Solar Cells

Researchers at the University of Nebraska-Lincoln have discovered that the same principle that makes some pans non-stick can be exploited to improve the performance of solar cells.

In research published in the journal Nature Communications, the researchers have built a perovskite-based solar cell on a “non-wetting” plastic, making it 1.5 times as efficient at energy conversion as such cells had been previously.

Previously, the best way to get better efficiency in solar cells was to use single crystal material because it has fewer grains—the tiny pieces whose barriers trap and prematurely recombine electrons and holes—than polycrystalline materials. This made for a tough choice: single crystal materials, which are costly and difficult to produce, or polycrystalline materials, whose energy conversion efficiency is comparatively low.

But the Nebraska team has come up with a third choice: polycrystalline materials with a reduced number of grains. That had been tried before, with limited success; the size of the grains was locked in direct proportion to the thickness of the polycrystalline film. But their new production method, featuring the non-wetting surface, dramatically improved the area-to-thickness ratio. The researchers discovered that if they grew the polycrystalline material on this non-wetting surface, the grains grew up to eight times larger than the cell is thick.

“We found that the difference is huge,” said Jingsong Huang, an associate professor of mechanical and materials engineering, in a press release. “When you have two small grains merge into a larger grain, what happens is that a boundary actually moves from (the middle of two grains) to the end of one or the other. How easily these boundaries move will determine how fast these grains can merge and grow.”

Huang added that “A non-wetting surface is slippery, like when you pour oil on a floor. It's easier for the grain boundary to move because we're reducing some of the drag force on it.”

The researchers believe that this use of a non-wetting surface can be exploited in other areas as well, such as aster transistors and more sensitive photodetectors.

Huang added: “When it comes to electronic properties, crystallinity and grain size determine a lot. So this is a simple method with a lot of potential applications.”

Self-Assembly Trick Embeds Quantum Dots Inside Nanowires

Self-assembling nanowires could give them a role in touch-screen displayssmoke detectors, and other applications.

Now researchers at the University of Cambridge in the UK in collaboration with IBM have developed a self-assembly process for nanowires that makes it possible to embed quantum dots within them, expanding their range of potential applications.

“The key to building functional nanoscale devices is to control materials and their interfaces at the atomic level,” said Stephan Hofmann of the University of Cambridge and one of the paper’s senior authors, in a press release. “We’ve developed a method of engineering inclusions of different materials so that we can make complex structures in a very precise way.”

The new self-assembly technique, which is described in the journal Nature Materials, is based on the typical process for producing nanowires: vapor-liquid-solid (VLS) synthesis.  VLS offers a fast way for producing nanowires based on chemical vapor deposition.

In VLS, chemical vapors disolve into a droplet of liquid catalyst. The chemicals crystalize at the base of the droplet, forming the nanowire, which pushes the catalyst up as it grows. Over the years, VLS has developed into a highly controlled process in which every detail of the nanowires from its size to its crystal structure can be precisely controlled.

The Cambridge researchers were able to build upon the VLS technique by using the catalyst droplet as a “mixing bowl” to add materials that lead to new growth phases. These new phases take the shape of faceted nanocrystals, or quantum dots.

“The technique allows two different materials to be incorporated into the same nanowire, even if the lattice structures of the two crystals don’t perfectly match,” said Hofmann. “It’s a flexible platform that can be used for different technologies.”

The inclusion of quantum dots in the nanowires would seem to indicate potential optoelectronic applications, for which the nanocrystals are well known. For example, the researchers anticipate that these new nanowires could find use in semiconductor lasers and other light emitters.

Two Great Photovoltaic Materials Brought Together Make Better LEDs

Ted Sargent at the University of Toronto has built a reputation over the years as being a prominent advocate for the use of quantum dots in photovoltaics. Sargent has even penned a piece for IEEE Spectrum covering the topic, and this blog has covered his record breaking efforts at boosting the conversion efficiency of quantum dot-based photovoltaics a few times.

Earlier this year, however, Sargent started to take an interest in the hot material that has the photovoltaics community buzzing: perovskite. Now, he and his research team at the University of Toronto have combined perovskite and quantum dots  into a hybrid that they believe could transform LED technology.

In research published in the journal Nature, Sargent’s team describes how they developed a way to embed the quantum dots in the perovskite so that electrons are funneled into the quantum dots, which then convert electricity into light.

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Perovskite Solar Cell Production Gets Environmentally Friendly

While perovskite has begun to branch out into transistors and nanowire lasers, it already has a stellar reputation as an alternative to silicon in photovoltaics.

However, perovskite’s rise to glory in the field of solar cells has not come without a few hiccups. One of the key problems has been that the production processes for making the material involves some toxic lead compounds.

Now researchers at the Karlsruhe Institute of Technology (KIT) are leading a three-year project dubbed “Nanosolar” that both seeks to address this issue and to reduce material consumption and thereby production costs.

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The Capabilities of Nanomaterials in Textiles Continue to Expand

The story of nanomaterials in textiles dates back at least to the formation of the National Nanotechnology Initiative (NNI) at the beginning of the 21st Century, when Nanotex was the NNI’s poster company for the new exciting world of nanotechnology.

The role of nanomaterials in textiles has evolved since then from comparatively simple hydrophobic materials that Nanotex continues to  produce to where we now are creating textile electrodes using graphene or weaving nanowires into t-shirts to make them into supercapacitors.

Perhaps the greatest metric of how far nanomaterials have come in textiles is the range of work being done by students at Cornell University where they are using a variety of different nanomaterials in combination with cotton to create clothing that kills bacteria, conducts electricity, and serves as a platform for electronic devices.

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First Transistor Fabricated From Black-Arsenic Phosphorus

An international team of researchers from Germany and the US have fabricated for the first time a field effect transistor made of black-arsenic phosphorus.

In research published in the journal Advanced Materials, the researchers from the Technical University of Munich (TUM) and the University of Regensburg in Germany and the University of Southern California (USC) and Yale University in the United States have developed a new method for synthesizing black-arsenic phosphorous that doesn’t require the high pressure typically needed, lowering energy requirements for the process and thereby costs.

Black phosphorus has been around for about 100 years, but recently it has been synthesized as a two-dimensional material—dubbed phosphorene in reference to its two-dimensional cousin, graphene. Black phosphorus is quite attractive for electronic applications like field-effect transistors because of its inherent band gap and it is one of the few 2-D materials to be a natively p-type semiconductor.

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IEEE Spectrum’s nanotechnology blog, featuring news and analysis about the development, applications, and future of science and technology at the nanoscale.

Dexter Johnson
Madrid, Spain
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