Silicon Slivers for Flexible Circuits

Printing CMOS on plastic

PHOTO: John A. Rogers/University of Illinois at Urbana-Champaign

Plastic power

Ring oscillators [left] and inverter circuits [middle and right] made of silicon ribbons printed on plastic.

Silicon circuits that bend and stretch recently took an important step away from the world of science-fiction novels and Hollywood movies toward the real world of medical devices and media players.

A team of researchers at the University of Illinois at Urbana-Champaign (UIUC) says it has printed silicon circuits onto plastic in the form of the same CMOS circuits that dominate digital logic today. The ­breakthrough brings researchers closer to printing circuits on plastic that approach the performance and reliability of silicon chips.

The team, led by materials ­science and chemistry ­professor John A. Rogers, had earlier shown that they could form ­circuits by transferring thin ribbons of ­silicon onto glue-coated plastic using a patterned rubber stamp. But the resulting devices used only n -type silicon, whereas CMOS logic has both n -type and p â''type. CMOS circuits are ­generally more power-efficient, because current should flow through them only when their bits are flipping. In any portable electronic device, that means longer battery life. But in the case of plastic ­electronics, CMOS is even more important, because it reduces the amount of heat produced—which, left unchecked, could melt the plastic.

Rogers’s research, which was reported in January in IEEE Electron Device Letters , also showed that printed ­plastic ­circuits can reach speeds matching those of ­silicon chips. Rogers says his group has built silicon circuits on plastic that switch at about 500 megahertz, five times as fast as the clock in a 1995 Pentium microprocessor. ”And there’s no fundamental reason you couldn’t go much higher,” he says.

The speed of these circuits greatly outstrips those made using organic ­semiconductors, a key competitor in the ­plastic ­electronics race. The main ­problem of organics is ­inherently low charge-carrier mobility, the metric describing the speed at which charges move through a material. The best organics have mobilities of about 1 square centi­meter per volt ­second versus 85 cm2/Vs for Rogers’s CMOS circuits.

The UIUC group’s ­technology also ­competes with plastic circuits made from semiconductor ­nanowires, such as those under ­development at Palo Alto, Calif.–based Nanosys. Instead of etching off ­ribbons of semi­conductor from a wafer as the Illinois group does, Nanosys and its partners ­chemically ­synthesize silicon ­nano­wires by means of vapor deposition.

The UIUC and Nanosys approaches ”are similar conceptually in that they take advantage of the fact that single-­crystal silicon is a good material for charge transport compared with, say, organics,” says Rogers. ”And they both use silicon structures small enough so that they are flexible and can be integrated with plastic.” But Rogers is convinced that ­making your own silicon when high-­quality wafers are commercially available adds an unnecessary complication to the ­manufacturing process. Citing confidentiality agreements with Nanosys’s ­commercial partners, the ­company’s cofounder and vice president of business development, Stephen Empedocles, declined to make direct comparisons between the Nanosys and UIUC approaches.

Rogers’s technology is under development at Semprius, a startâ''up based in Durham, N.C., of which he is cofounder. Besides refining the ­manufacturing ­process, Semprius is ­working on making silicon-based ­electronics that are not only bendable but ­stretchable. That involves ­making the ­silicon thin and then ­structuring ”the material into a wavy shape so it becomes like the bellows on an ­accordion,” says Rogers. One ­application the company is ­investigating is putting the stretchy circuits on spheres for electronic eye–type imaging systems.

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