Illustration: Bryan Christie Design
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In 1995, a small
fleet of innovative electric buses began
running along 15-minute routes through a park at the
northern end of Moscow. A decade later, a few dozen
seaport cranes in Asia, a couple of light-rail trains in
Europe, and a battalion of garbage trucks in the United
States have joined their high-tech ranks.
A smattering of mass-transit vehicles and industrial
machines may seem like one wimpy revolution, but
revolutionary they are. Unlike most of their electric
relatives, these vehicles all share one key attribute:
they don't run on batteries. Instead, they are powered
by ultracapacitors, which are souped-up versions of that
tried-and-true workhorse of electrical engineering, the capacitor.
A bank of ultracapacitors releases a burst of energy
to help a crane heave its load aloft; they then capture
energy released during the descent to recharge. Buses,
trams, and garbage trucks powered by the devices all run
for short stretches before stopping, and it's during
braking that the ultracapacitors can partially recharge
themselves from the energy that's normally wasted,
giving the vehicles much of the juice they need to get
to their next destinations.
Because no chemical reaction is involved,
ultracapacitors—also known as supercapacitors and
double-layer capacitors—are much more effective at
rapid, regenerative energy storage than chemical
batteries are. What's more, rechargeable batteries
usually degrade within a few thousand charge-discharge
cycles. In a given year, a light-rail vehicle might go
through as many as 300 000 charging cycles, which is far
more than a battery can handle. (Although flywheel
energy-storage systems can be used to get around that
difficulty, a heavy and complicated transmission system
is needed to transfer the energy.)
The synergy between batteries and capacitors—two of
the sturdiest and oldest components of electrical
engineering—has been growing, to the point where
ultracapacitors may soon be almost as indispensable to
portable electricity as batteries are now.
Ultracapacitors are already all over the place.
Millions of them provide backup power for the memory
used in microcomputers and cellphones. They also supply
brief bursts of energy to numerous consumer products
containing batteries. In a camera, for example, an
ultracapacitor can extend battery life by providing the
oomph for power-intensive functions, like zooming in for
a close-up.
Perhaps most exciting is what ultracapacitors could do
for electric cars. They're being explored as
replacements for the batteries in hybrid cars. In
ordinary cars, they could help level the load on the
battery by powering acceleration and recovering energy
during braking. Most deadly to the life of a battery are
the moments when it is subjected to high-current pulses
and charged or discharged too quickly. Conveniently,
delivering or accepting power during short-duration
events is the ultracapacitor's strongest suit. And
because capacitors function well in temperatures as low
as –40 ºC, they can give electric cars a boost in cold
weather, when batteries are at their worst.
Commercially available ultracapacitors already address
those needs to some extent and can provide many times
the power of batteries of the same weight or size. But
in terms of the amount of energy they can hold,
ultracapacitors lag far behind. The major difference is
that batteries store energy in the bulk of their
material, whereas all forms of capacitors store energy
only on the surface of a material. Like a battery, an
ultracapacitor is filled with an ionic solution—an
electrolyte—and its current collectors attach to the
electrodes and conduct current to and from them. The
collectors are coated with a thin film of activated
carbon that has orders of magnitude more surface area
than ordinary capacitors. The amount of surface area in
ultracapacitor designs has so far been constrained by
the limitations in the porosity of the activated carbon.
The innovation that my colleagues John Kassakian and
Riccardo Signorelli and I have pursued at MIT is to
replace the activated carbon with a dense, microscopic
forest of carbon nanotubes that is grown directly on the
surface of the current collector. We think—and our work
so far supports our theory—that by doing so, we can
create a device that can hold up to 50 percent as much
electrical energy as a comparably sized battery. This
feat would allow ultracapacitors to supplant batteries
in a number of mainstream applications.