Image: Mark Hooper
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In 1982, Krishna Persaud and George Dodd at the
University of Warwick, in Coventry, England, put
together the first sensor array for odor
recognition—that is, a collection of electronic
sensors, each of which responded in different ways to a
range of volatile chemicals. Persaud and Dodd used
oscillating semiconducting transducers that changed
frequency when they detected certain compounds.
In 1988, Julian Gardner, also at the University of
Warwick, dubbed this approach the electronic nose.
Rather than cataloging the chemical compounds of an
odor, an e-nose identifies complex odors by using
pattern-recognition strategies similar to those of the
human olfactory system, albeit with different sensing
mechanisms. Given a glass of wine, the average person
knows from the smell alone what the liquid is. But only
a serious oenophile might be able to break the odor down
into its constituent parts: alcohols, acids, and esters.
The human nose has hundreds of different types of odor
sensors, whose response patterns are processed by the
brain, which then searches its memory for matches to
stored response patterns. An electronic nose uses far
fewer sensors; commercial systems have around 10 to 50
sensing elements.
Your typical e-nose consists of a sampling system, a
gas-sensor array, and a signal processor coupled to a
pattern-recognition system of some sort. The sampling
system brings vapor-laden air into the sensor array; in
a laboratory setup it might have a fan that blows air
across the array in an action reminiscent of human
sniffing. The nose might allow a vial of air to be
released inside it; perfume makers capture samples this
way. Or it might work passively, simply because the
array is exposed, like the sensor in a smoke detector.
In the sensor array, each of the sensors responds to a
broad range of gases, with much duplication; multiple
sensors will respond to the same gas, but not in the
same way, and not to all the same gases. To identify
specific odors requires the signal processor to analyze
the array response with pattern-recognition algorithms;
in today's expensive electronic noses, a microprocessor
uses a large set of stored algorithms to sort through
patterns. In the future, however, single-purpose noses
looking for a simple change—food gone bad, for
example—could use application-specific integrated
circuits for analysis.
Much like that of the human nose, this type of odor
recognition is more flexible and more powerful than what
is possible with a lock-and-key sensor, which can detect
only a single compound, say, carbon monoxide. Such a
sensor would have a hard time telling the difference
between Grandma's apple pie and Mom's. But it may be
possible to train an array-type e-nose to discriminate
between them and all other apple pies.
And unlike systems based on lock-and-key sensors,
electronic noses can be enormously flexible. Rather than
developing one nose for wine monitoring and a different
one to detect bad fish, the same piece of hardware could
be trained separately for different tasks. Imagine an
electronic-nose system shipped with standard
pattern-recognition libraries. Load up one for the
refrigerator and the system will sniff for spoiling
foodstuffs; load up a different one for the garden and
the system searches instead for the telltale odors of
snails and other pests. And what if you want the e-nose
to learn the difference between Grandma's apple pie and
Mom's? Well, chances are the manufacturers will have
never met Grandma or Mom or sampled the output of their
ovens. But they may have included software for
generating new pattern-recognition libraries. If so, you
would hook up the nose to the training system, introduce
it to one apple pie at a time, and find out if the pies
generate distinguishable responses in the array. If they
do, then generate a new library, load it up, and you've
got a personalized apple- pie connoisseur.